da European Commission

Poly- and perfluoroalkyl substances (PFAS)

What are PFAS: properties, uses, concerns and sources of emissions
Poly- and perfluoroalkyl substances (PFAS) are a group of widely used man-made organic chemical substances.

They contain alkyl groups on which all or many of the hydrogen atoms have been replaced with fluorine. Well known PFAS contain fully fluorinated carbon chains of various chain lengths attached to a functional group, like carboxylic or sulfonic acids. Such groups are called perfluorinated acids and include PFOA and PFOS. Shorter chain PFAS have been developed more recently to substitute the longer chain ones. In this context, an important distinction is the one between “long chain” and “short chain” PFAS.
The PFAS group includes also polymers: e.g. fluoropolymers, perfluoropolyethers and side-chain fluorinated polymers.
The OECD has published a clear explanation of the different groups of PFAS. Examples of typical PFAS structures are shown in Figure 1.

  

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